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Traductions de „lone pair“ dans le dictionnaire anglais » arabe (Aller à arabe » anglais)

Exemples monolingues (non-vérifiés par l'équipe de rédaction)

anglais
Unlike the related 5-membered heterocycles pyrrole, thiophene, and furan, the aromaticity of phospholes is diminished, reflecting the reluctance of phosphorus to delocalize its lone pair.
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Nevertheless, the lone pair of the nitrogen, responsible of the zwitterionic structure, stabilizes the structure and is responsible of the linearity of isocyanides.
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Interestingly, the migrating substituent is determined by a stereoelectronic effect where the group trans to the lone pair on the nitrogen will always be the predominant migration product.
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Whereas the lone pair on nitrogen is delocalized in pyrrole, the lone pair on phosphorus atom in the phosphorus equivalent of pyrrole (phosphole) is not.
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The synthesis of the axial diastereomer is rationalized via the 1,3-anomeric effect which reduces the nucleophilicity of the equatorial lone pair.
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