Traductions de „cyclization“ dans le dictionnaire russe » anglais

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циклиза́ция

cyclization

Exemples monolingues (non-vérifiés par l'équipe de rédaction)

anglais

Metal-catalyzed cyclization reactions usually require mildly basic conditions, and substrates must be chosen to avoid -hydride elimination.

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The cyclization of -epoxy-1-nitriles provides an interesting example of how stereoelectronic factors may override steric factors in intramolecular substitution reactions.

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Both lanosterol and cycloartenol are derived via cyclization of the triterpenoid squalene.

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A classic example is the cyclization of geranyl pyrophosphate to form limonene.

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The dimethylallyl group in 7 then undergoes cyclization with the phenol group to give 8.

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In this pathway, vinblastine is constructed by a series of cyclization and coupling reactions which create the required stereochemistry.

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Other applications include use in alkylation reactions and as a catalyst component in linear oligomerization and cyclization of unsaturated hydrocarbons.

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The resulting o-benzoylbenzoic acid then undergoes cyclization, forming anthraquinone.

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Approaches to this synthesis are diverse, and include central steps such as annululation, olefin metathesis, radical cyclization, and trapping reactions.

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The polyketide chain produced is electronically capable to go through a lactonization and a diels alder cyclization, as shown below.

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